PHOTOELECTRONIC INVESTIGATION OF Pd ELECTRON STRUCTURE TRANSFORMATION AT OXYGEN ADSORPTION
Oxygen adsorption on the surface of polycrystalline palladium has been studied by the photoelectron spectroscopy method in a wide range of oxygen exposure and temperatures, starting with the earliest stages of adsorption to the formation of the surface compound of PdO-type. Based on the analysis of the experimental data and the calculation of the density of states carried out by the TB-LMTO-ASA method, the attempt to elucidate the electronic mechanism of adsorption and oxidation power of palladium was made.
Year of publication: |
2005
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Authors: | BELASH, V. P. ; KLIMOVA, I. N. ; MITROKHIN, Yu. S. |
Published in: |
Surface Review and Letters (SRL). - World Scientific Publishing Co. Pte. Ltd., ISSN 1793-6667. - Vol. 12.2005, 05, p. 713-719
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Publisher: |
World Scientific Publishing Co. Pte. Ltd. |
Subject: | Photoelectron spectra | adsorption | electronic structure | Fermi level |
Saved in:
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