Using the liquid state thermodynamic perturbation theory and the hard-sphere fluid as the reference system, the liquid–glass transition line of Lennard–Jones and hard-core Yukawa fluids is computed. The results are presented both in the reduced density vs. reduced temperature and in the...

A generalization of extended irreversible thermodynamics is obtained by including the gradients of conserved and nonconserved variables in the space of thermodynamical states. The relaxation equations for these additional state variables are derived systematically from the basic postulates of...