Martinez, Luz-Maria; Angell, C. Austen - In: Physica A: Statistical Mechanics and its Applications 314 (2002) 1, pp. 548-559
fluctuations that determine the structural relaxation time, and hence the glass transition temperature. Using a spectroscopically … active chemical order probe, we identify a “chemical fictive temperature”, Tchm, by analogy with the “fictive temperature” Tf … commonly used to denote the temperature where the structural arrest occurred during cooling a glassformer. Like Tf, Tchm must …