Showing 1 - 6 of 6
The longitudinal relaxation time and the complex dielectric polarizability of rod-like molecules with dipole moment parallel to the long axis in a biaxial nematic liquid crystal are calculated using as model the rotational Brownian motion in a mean field potential so reducing the problem to a...
Persistent link: https://www.econbiz.de/10010591611
The rotational correlation function of anisotropic colloidal particles can be measured by observing the fluctuations of the depolarized intensity scattered in the forward direction. In this work we present a theoretical treatment of forward depolarized light scattering. Our calculations show the...
Persistent link: https://www.econbiz.de/10010586546
A systematic framework introduced recently to obtain parameter-free predictions of material properties of dilute polymer solutions in extensional flows is reviewed. The essential constraint of ensuring that the model polymer molecule has a finite length is met by using a bead–spring chain...
Persistent link: https://www.econbiz.de/10010874058
We studied the hydrodynamic interaction between a colloidal particle close to flat rigid boundaries and the surrounding fluid using oscillating optical tweezers. A colloidal particle located near walls provides a model system to study the behavior of more complex systems whose boundaries can be...
Persistent link: https://www.econbiz.de/10010679190
In the framework of a linear response theory, in which Onsager’s continuity equations are combined with the Mean Spherical Approximation (MSA) from the theory of correlation functions in equilibrium, and using a Green’s function formalism, we consider the transport properties of...
Persistent link: https://www.econbiz.de/10010709972
Based on the Wilemski–Fixman approach [G. Wilemski, M. Fixman, J. Chem. Phys. 60 (1974) 866], we show that, for a flexible chain in θ solvent, hydrodynamic interaction treated with a pre-averaging approximation makes ring closing faster if the chain is not very short. We also show that the...
Persistent link: https://www.econbiz.de/10011061001