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Kinetics of the adsorption process with diffusional relaxation is studied by Monte Carlo simulation on a square lattice. Depositing objects are squares covering nine lattice sites. At each Monte Carlo step, adsorption is attempted with probability Pa and diffusion with probability Pdif=1−Pa....
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desorption with probability Pdes=1−Pa. The equilibrium coverage and the relaxation time are obtained for various ratios of the … power law σ∝(Pa/Pdes)2. The equilibrium coverage decreases exponentially with Pdes/Pa for low desorption probabilities. …
Persistent link: https://www.econbiz.de/10011062457
equilibrium coverage is not affected by the diffusion rate, while the diffusion fastens the approach to the equilibrium state …
Persistent link: https://www.econbiz.de/10011063727