Showing 1 - 10 of 18
We survey a collection of statistical-mechanical problems involving systems inhomogeneous (only) in one spatial direction and seldom discussed by way of a unified treatment. We employ a Landau density functional approach and present the analysis with the help of the equivalent nonlinear...
Persistent link: https://www.econbiz.de/10010872913
We study the stability of planar, cylindrical and spherical interfaces with respect to shape and width fluctuations for a model amphiphile solution described by a free energy density functional with square-gradient and square-Laplacian terms. That is, we determine the stability matrix when the...
Persistent link: https://www.econbiz.de/10010874547
Persistent link: https://www.econbiz.de/10009281918
The derivation from first principles of the elastic curvature free energy, or Helfrich free energy, of a nonplanar interface demands a detailed cross-examination and call in question of the statistical-mechanical basis of the theory of nonplamar interfaces. Here we give an account that (i)...
Persistent link: https://www.econbiz.de/10010587482
A comprehensive description of interfaces containing amphiphiles has been developed through the use of a free energy density functional with squared-gradient and squared-Laplacian terms. This elemental model functional contains the basic ingredients for the problem, it is technically tractable...
Persistent link: https://www.econbiz.de/10010589313
Recently, in [Phys. Rev. Lett. 95 (2005) 140601], Grassberger addresses the interesting issue of the applicability of q-statistics to the renowned Feigenbaum attractor. He concludes there is no genuine connection between the dynamics at the critical attractor and the generalized statistics and...
Persistent link: https://www.econbiz.de/10010589787
A random-walk formalism is applied to some general Ornstein-Zernike lattice systems to obtain information as to the asymptotic form of the total correlation function. Calculations in terms of the Percus-Yevick approximation are then presented for certain lattice gases with interactions extending...
Persistent link: https://www.econbiz.de/10010584970
The random-walk formalism that describes correlation functions in a homogenous system is here extended to cover correlations in ordered phases of a lattice gas. The general method is illustrated by application to certain lattice gases on linear, square and honeycomb lattices, treated under the...
Persistent link: https://www.econbiz.de/10010585012
An exact non-equilibrium Ornstein-Zernike (OZ) equation is derived for lattice fluid systems whose time development is given by a generalized master equation. The derivation is based on a generalization of the Montroll-Weiss continuous-time random walk on a lattice, and on their relationship...
Persistent link: https://www.econbiz.de/10010585060
As a step towards a random-process formulation for classical fluids which ivolve many-body correlations, a random-walk formulation is presented wherein, for both lattice-gas and continuum models, the Green function and weight function describing the random walk are related to the total...
Persistent link: https://www.econbiz.de/10010585063