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The multipolar square-well (MSW) fluid treated in part I [Physica A 202 (1994) 420] is studied in order to analyze the effect of SW range λ, which models the range of dispersion forces, on the vapor-liquid (VL) equilibrium. The model includes a simpler and more accurate treatment of the SW...
Persistent link: https://www.econbiz.de/10011063710
A simple polar fluid is modelled by square-well particles with point dipoles and quadrupoles at their centers. An equation for the free energy is derived by perturbation theory, obtaining the explicit dependence on the potential parameters, and allowing to study the effects of the strength of...
Persistent link: https://www.econbiz.de/10011057835