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Within the context of a general mode-coupling theory previously developed for the description of equilibrium fluctuations in simple classical fluids, we derive an expression for the effective longitudinal viscosity includings couplings to currents so that certain key assumptions inherent in...
Persistent link: https://www.econbiz.de/10010586936
Under the assumption that structural relaxation is dominated by the decay of clusters of particles, we develop a microscopic theory for transport in a strongly supercooled liquid. By introducing a local order parameter that describes the geometry of particle aggregates in addition to the number...
Persistent link: https://www.econbiz.de/10010587502