O2-release from carbon-bearing Ni(II) ferrite (CBNF) was studied with TG-MS and DSC. Release of lattice oxygen as O2 was found to take place at 200–300°C and was associated with an endothermic temperature peak. The proposed thermochemical reaction is Olat.(s) = Vö(s) + (12) O2(g), ΔH° =...

The praseodymium oxide redox system releases and incorporates oxygen into an inert gas. Reductions of Pr6O11 to Pr5O9 and Pr5O9 to Pr9O16 were analyzed while heating a mixture of air with N2 at O2 partial pressures of 2 × 102-6 × 103 Pa from 373 to 833 K. Oxidations of Pr9O16 to Pr5O9 and...

An endothermic chemical system composed of pulverized metal oxide and carbon has been investigated with a view to utilizing waste heat and carbonaceous compounds effectively. Oxides of Cu and Mn and also MMn2O4 (M = Li or Mg) were used. In an N2-gas stream, the metal oxide was reduced by...