Showing 1 - 10 of 31
A new viewpoint on the kinetics of Ostwald ripening is presented by studying the kinetic equation recently derived for the late stage of phase separation. It is shown that the average droplet radius grows as t13 and the number density of droplets decays as t-1. An important effect of a soft...
Persistent link: https://www.econbiz.de/10010872825
We investigate the dynamics of phase separations in quenched binary mixtures, such as binary alloys and polymer blends with low mobilities, at higher volume fractions. Computer simulations are performed using simple model equations in the presence of encounters of droplets. Four characteristics...
Persistent link: https://www.econbiz.de/10010874635
The time-convolutionless mode-coupling theory (TMCT) equation for the intermediate scattering function fα(q,t) derived recently by the present author is analyzed mathematically and numerically, where α=c stands for a collective case and α=s for a self case. All the mathematical formulations...
Persistent link: https://www.econbiz.de/10011264568
The experimental and the simulation results for the mean-square displacements in eight different systems (four suspensions of colloids and four molecular systems) are analyzed near their glass transitions by the mean-field theory recently proposed. The dependence of various physical quantities...
Persistent link: https://www.econbiz.de/10010588669
The short-time self-diffusion of highly charged colloids is studied theoretically. Generalized Langevin equations for the momenta of colloids are derived from a statistical–mechanical point of view. The mean-square displacement of colloids is then calculated for short times. The finite size...
Persistent link: https://www.econbiz.de/10010588827
A formal theory of finding a nonlinear stochastic diffusion equation for density fluctuations in a suspension of colloidal hard spheres, which enables us to study the influence of solvent-mediated hydrodynamic interactions between particles as well as the direct interactions, is presented with...
Persistent link: https://www.econbiz.de/10010589138
Slow dynamics of equilibrium hard-sphere colloidal suspensions near the glass transition is discussed from a new viewpoint by numerically solving a cubic nonlinear stochastic diffusion equation for the density fluctuation recently proposed by one of the present authors (MT). The important role...
Persistent link: https://www.econbiz.de/10010589801
A statistical-mechanical theory of slow dynamics near the glass transition in two kinds of glass-forming systems, (M) molecular systems and (S) suspensions of colloids, is presented from a unified point of view based on the Tokuyama–Mori projection operator method. The exact diffusion...
Persistent link: https://www.econbiz.de/10010589852
Brownian-dynamics simulations are performed on highly charged colloidal suspensions by employing an effective attractive force between colloids proposed recently by Tokuyama (Phys. Rev. E 59 (1999) R2550; Phys. Rev. E 58 (1998) R2729). In addition to a gas phase, two novel droplet phases are shown...
Persistent link: https://www.econbiz.de/10010591507
A new statistical-dynamical theory of nonlinear stochastic processes in nonequilibrium open systems is presented. It is shown by means of the time-convolutionless projector method that multiplicative type stochastic equations of motion for relevant variables Ai(t) can always be transformed...
Persistent link: https://www.econbiz.de/10010584803