Showing 1 - 10 of 21
The quasi-equilibrium or maximum entropy approximation is applied in order to derive constitutive equations from kinetic models of polymer dynamics. It is shown in general and illustrated for an example how canonical distribution functions are obtained from the maximum entropy principle, how...
Persistent link: https://www.econbiz.de/10011060168
The main goal of this paper is a rigorous consideration of the stress problem in some simple models of granular piles. Discrete models are considered and the transition to the continuous description is accomplished in order to find the coarse-grained average stress. Some phenomenological rules...
Persistent link: https://www.econbiz.de/10010588735
We discuss the kinetic representation of gases and the derivation of macroscopic equations governing the thermomechanical behavior of a dilute gas viewed at the macroscopic level as a continuous medium. We introduce an approach to kinetic theory where spatial distributions of the molecules are...
Persistent link: https://www.econbiz.de/10010591790
The viscosity of slag and the thermal conductivity of ash deposits are among two of the most important constitutive parameters that need to be studied. The accurate formulation or representations of the (transport) properties of coal present a special challenge of modeling efforts in...
Persistent link: https://www.econbiz.de/10011031197
The method of invariant manifold is developed for a derivation of reduced description in kinetic equations of dilute polymeric solutions. It is demonstrated that this reduced description becomes universal in the limit of small Deborah and Weissenberg numbers, and it is represented by the...
Persistent link: https://www.econbiz.de/10010873916
We find fundamental solutions in closed form for a family of parabolic equations with two spatial variables, whose symmetry groups had been determined in an earlier paper by Finkel [12]. We show how these results can be applied in finance to yield closed form solutions for special affine and...
Persistent link: https://www.econbiz.de/10004971804
We show how to coarse-grain polymers in a good solvent as single particles, interacting with density-independent or density-dependent interactions. These interactions can be between the centres of mass, the mid- or end-points of the polymers. We also show how to extend these methods to polymers...
Persistent link: https://www.econbiz.de/10010589794
The proton binding characteristics of ionizable interfaces and linear polyelectrolytes are different. While ionizable interfaces protonate in a single broad protonation step, linear polyelectrolytes often show distinct two-step protonation behavior. We explain this phenomenon on the basis of a...
Persistent link: https://www.econbiz.de/10010591845
Diffusion of transported particles in the intracellular medium is described by means of a generalized diffusion equation containing forces due to the cytoskeleton network and to the protein motors. We find that the enhanced diffusion observed in experiments depends on the nature of the force...
Persistent link: https://www.econbiz.de/10011057194
We present a kinetic theory for one-dimensional inhomogeneous systems with weak long-range interactions. Starting from the Klimontovich equation and using a quasilinear theory valid at order 1/N in a proper thermodynamic limit N→+∞, we obtain a closed kinetic equation describing the...
Persistent link: https://www.econbiz.de/10011057970