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A Mori-type equation for the lattice concentration of an interacting lattice gas is constructed on the basis of the master equation in the framework of the nonequilibrium statistical ensemble method due to Zubarev. The general expression for the diffusion coefficient, which takes into account...
Persistent link: https://www.econbiz.de/10010872525
A variational approach to collective diffusion in the interacting lattice gas, based on kinetics of microscopic states of the system, is presented. The approach accounts for equilibrium correlations and is capable of predicting the coverage dependence of the diffusion coefficient D(θ) in an...
Persistent link: https://www.econbiz.de/10011063010
Controlled release of nutrients from coated fertilizer granules is desired for optimal uptake by plants and crops. We study the saturation and release of nutrients from a coated spherical fertilizer granule having varying contact areas with the soil using the techniques of mathematical modeling...
Persistent link: https://www.econbiz.de/10010748814
The solution of the diffusion equation at the non-stationary boundary represents the so-called Stefan problem which can be solved by means of the thermal potential of a double-layer with the accuracy sufficient for description of diffusion phenomena. The results were methods for determination of...
Persistent link: https://www.econbiz.de/10011051031