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An analytical description of the nucleation stage in a supersaturated vapor with instantly created supersaturation is given with taking into account the vapor concentration inhomogeneities arising as a result of depletion due to nonstationary diffusion onto growing droplets. This description is...
Persistent link: https://www.econbiz.de/10010872342
We examine some aspects of the recent results by Binder [Physica A 319 (2003) 99]. The equilibrium formation/dissolution of droplets in finite systems is discussed in the context of the canonical and the grand canonical distributions.
Persistent link: https://www.econbiz.de/10011064230
In their comment to the paper “Theory of the evaporation/condensation transition of equilibrium droplets in finite volumes” [Physica A 319 (2003) 99], Biskup et al. claim that in finite systems at fixed density “the physical significance of the conjugate thermodynamic variable is of...
Persistent link: https://www.econbiz.de/10011059776
A phenomenological theory of phase coexistence of finite systems near the coexistence curve that occurs in the thermodynamic limit is formulated for the generic case of d-dimensional ferromagnetic Ising lattices of linear dimension L with magnetization m slightly less than mcoex. It is argued...
Persistent link: https://www.econbiz.de/10011060128