Showing 1 - 10 of 13
By introducing an order parameter that describes the geometry of clusters of particles, Liu and Oppenheim [Physica A 247 (1997) 183] developed a microscopic theory for hopping transport in glass-forming liquids. In this work we bring this theory within the frame of mode coupling theories in the...
Persistent link: https://www.econbiz.de/10010871696
Within the context of a general mode-coupling theory previously developed for the description of equilibrium fluctuations in simple classical fluids, we derive an expression for the effective longitudinal viscosity includings couplings to currents so that certain key assumptions inherent in...
Persistent link: https://www.econbiz.de/10010586936
The extensive molecular-dynamics simulations on binary mixtures A80B20 with a Stillinger–Weber potential are performed to obtain two types of glass-forming liquids near the glass transition, fragile and strong liquids. The simulations are done for different mass ratios Q(=mB/mA) under the same...
Persistent link: https://www.econbiz.de/10011062537
This paper compares simulation and experiment to verify how a hard-sphere fluid is different from a suspension of hard-sphere colloids near the glass transition at 6% polydispersity. This is done by performing extensive molecular-dynamic simulations and by analyzing the resultant mean-square...
Persistent link: https://www.econbiz.de/10011063610
A statistical-mechanical theory of self-diffusion in colloidal suspensions is presented. A renormalized linear Langevin equation is derived from a nonlinear Langevin equation by employing the Tokuyama–Mori projection operator method. The friction constant is thus shown to be renormalized by...
Persistent link: https://www.econbiz.de/10011063837
A statistical-mechanical theory of slow dynamics near the glass transition in two kinds of glass-forming systems, (M) molecular systems and (S) suspensions of colloids, is presented from a unified point of view based on the Tokuyama–Mori projection operator method. The exact diffusion...
Persistent link: https://www.econbiz.de/10010589852
Extensive molecular-dynamics simulations on two different glass-forming systems are performed to test the prediction proposed recently by the mean-field theory (MFT) of glass transition that a fragile system can be mimicked by a simpler one near their glass transitions. One is a simulation for a...
Persistent link: https://www.econbiz.de/10011057179
The experimental and the simulation results for the mean-square displacements in various systems are analyzed near glass transitions by employing the mean-field theory recently proposed. By comparing different glass transitions with each other from a unified point view, it is then shown that the...
Persistent link: https://www.econbiz.de/10011057677
The time-convolutionless mode-coupling theory (TMCT) equation for the intermediate scattering function fα(q,t) derived recently by the present author is analyzed mathematically and numerically, where α=c stands for a collective case and α=s for a self case. All the mathematical formulations...
Persistent link: https://www.econbiz.de/10011264568
The Tokuyama–Mori type projection-operator method is employed to study the dynamics of nonlinear density fluctuations near the glass transition. A linear non-Markov time-convolutionless equation for the scattering function Fα(q,t) is first derived from the Newton equation with the memory...
Persistent link: https://www.econbiz.de/10011061181