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The effects of spatial heterogeneities on the slow dynamics of density fluctuations are discussed both in an equilibrium colloidal suspension and in a slightly nonequilibrium colloidal suspension. The long-lived, heterogeneous glassy domains appear near the glass transition and influence the...
Persistent link: https://www.econbiz.de/10011062605
Slow dynamics of equilibrium hard-sphere colloidal suspensions near the glass transition is discussed from a new viewpoint by numerically solving a cubic nonlinear stochastic diffusion equation for the density fluctuation recently proposed by one of the present authors (MT). The important role...
Persistent link: https://www.econbiz.de/10010589801
A heuristic hypothesis is given for the colloidal glass transition on the basis of the theoretical analyses of experimental data from a unified viewpoint obtained recently by the present author. Three regions, a liquid region, a supercooled liquid region, and a glass region, are distinguished....
Persistent link: https://www.econbiz.de/10011059299
The importance of the dynamic anomaly of the self-diffusion coefficient, which becomes zero at the colloidal glass transition volume fraction φg as DS∼(1−Φ(x,t)/φg)2, has recently been emphasized for understanding structural slowing down in concentrated hard-sphere colloidal suspensions,...
Persistent link: https://www.econbiz.de/10011060085