Showing 11 - 20 of 31
The Tokuyama–Mori type projection-operator method is employed to study the dynamics of nonlinear density fluctuations near the glass transition. A linear non-Markov time-convolutionless equation for the scattering function Fα(q,t) is first derived from the Newton equation with the memory...
Persistent link: https://www.econbiz.de/10011061181
The numerical solutions of the mode-coupling equations for the Lennard-Jones binary colloids are investigated by extensive Brownian-dynamics simulations from a unified point of view based on the mean-field theory proposed recently by one of the present authors [M. Tokuyama, Physica A 378 (2007)...
Persistent link: https://www.econbiz.de/10011061388
Self-diffusion in multi-component glass-forming systems including fragile and strong glasses is studied from a unified viewpoint. A simple analytic form of long-time self-diffusion coefficient DSL is proposed. The equations for the mean-square displacements recently derived for two types of...
Persistent link: https://www.econbiz.de/10011061631
Two types of projection-operator methods, Mori type and Tokuyama–Mori type, are tested for studying the slow dynamics of a single particle in complex systems near the glass transition. From a unified point of view based on the mean-field theory recently proposed by the present author, the...
Persistent link: https://www.econbiz.de/10011062246
A new statistical-mechanical theory of diffusion-controlled droplet coarsening is presented. With the aid of a scaling expansion method, a spatial graining is carried out in a manner consistent with an expansion in droplet volume fraction φ to obtain kinetic equations for a single distribution...
Persistent link: https://www.econbiz.de/10011062278
A statistical-mechanical theory of self-diffusion in glass-forming liquids is presented. A non-Markov linear Langevin equation is derived from a Newton equation by employing the Tokuyama–Mori projection operator method. The memory function is explicitly written in terms of the force-force...
Persistent link: https://www.econbiz.de/10011062314
The extensive molecular-dynamics simulations on binary mixtures A80B20 with a Stillinger–Weber potential are performed to obtain two types of glass-forming liquids near the glass transition, fragile and strong liquids. The simulations are done for different mass ratios Q(=mB/mA) under the same...
Persistent link: https://www.econbiz.de/10011062537
The effects of spatial heterogeneities on the slow dynamics of density fluctuations are discussed both in an equilibrium colloidal suspension and in a slightly nonequilibrium colloidal suspension. The long-lived, heterogeneous glassy domains appear near the glass transition and influence the...
Persistent link: https://www.econbiz.de/10011062605
This paper compares simulation and experiment to verify how a hard-sphere fluid is different from a suspension of hard-sphere colloids near the glass transition at 6% polydispersity. This is done by performing extensive molecular-dynamic simulations and by analyzing the resultant mean-square...
Persistent link: https://www.econbiz.de/10011063610
A statistical-mechanical theory of self-diffusion in colloidal suspensions is presented. A renormalized linear Langevin equation is derived from a nonlinear Langevin equation by employing the Tokuyama–Mori projection operator method. The friction constant is thus shown to be renormalized by...
Persistent link: https://www.econbiz.de/10011063837