Showing 1 - 10 of 31
Slow dynamics of equilibrium hard-sphere colloidal suspensions near the glass transition is discussed from a new viewpoint by numerically solving a cubic nonlinear stochastic diffusion equation for the density fluctuation recently proposed by one of the present authors (MT). The important role...
Persistent link: https://www.econbiz.de/10010589801
We investigate how universal the collective behavior, due to the many-body interactions in polydisperse hard-sphere systems, is at higher volume fractions. We perform two types of computer simulations, a Brownian-dynamics simulation on colloidal suspensions of hard spheres, where the...
Persistent link: https://www.econbiz.de/10011059292
The effects of spatial heterogeneities on the slow dynamics of density fluctuations are discussed both in an equilibrium colloidal suspension and in a slightly nonequilibrium colloidal suspension. The long-lived, heterogeneous glassy domains appear near the glass transition and influence the...
Persistent link: https://www.econbiz.de/10011062605
This paper compares simulation and experiment to verify how a hard-sphere fluid is different from a suspension of hard-sphere colloids near the glass transition at 6% polydispersity. This is done by performing extensive molecular-dynamic simulations and by analyzing the resultant mean-square...
Persistent link: https://www.econbiz.de/10011063610
A direct and elementary derivation is presented for the kinetic equation of the single droplet distribution function and the variance equation that describe Ostwald ripening. The derivation is basically algebraical and the screening effects of diffusional interactions among droplets is taken...
Persistent link: https://www.econbiz.de/10010585193
The encounter effect on the dynamics of fluctuations in phase separations of off-critically quenched binary systems is studied by performing three-dimensional computer simulations of the droplet growth model proposed recently by the authors. The dynamical behavior of the scattering structure...
Persistent link: https://www.econbiz.de/10010586960
A simple theory for nonequilibrium density fluctuations in concentrated hard-sphere suspensions of interacting Brownian particles with both hydrodynamic and direct interactions is proposed. The correlation effects due to the many-body hydrodynamic interactions among particles are shown to cause...
Persistent link: https://www.econbiz.de/10010587152
The experimental and the simulation results for the mean-square displacements in eight different systems (four suspensions of colloids and four molecular systems) are analyzed near their glass transitions by the mean-field theory recently proposed. The dependence of various physical quantities...
Persistent link: https://www.econbiz.de/10010588669
The short-time self-diffusion of highly charged colloids is studied theoretically. Generalized Langevin equations for the momenta of colloids are derived from a statistical–mechanical point of view. The mean-square displacement of colloids is then calculated for short times. The finite size...
Persistent link: https://www.econbiz.de/10010588827
A formal theory of finding a nonlinear stochastic diffusion equation for density fluctuations in a suspension of colloidal hard spheres, which enables us to study the influence of solvent-mediated hydrodynamic interactions between particles as well as the direct interactions, is presented with...
Persistent link: https://www.econbiz.de/10010589138