Showing 1 - 10 of 17
We consider a collection of droplets during the late stage of phase separation in a closed system. Its coarsening is driven by surface energy and leads asymptotically to a linear growth of the mean droplet volume with time (Ostwald ripening). The droplets grow either from the supersaturated...
Persistent link: https://www.econbiz.de/10011057628
We consider a collection of droplets growing from a supersaturated vapor or (in general fluid) solution for the time well after the nucleation. Its coarsening is driven by surface energy and leads asymptotically to a linear growth of the mean droplet volume with time (Ostwald ripening). The...
Persistent link: https://www.econbiz.de/10011057925
We consider linear systems in which some of the variables evolve on a much faster time scale than the remaining ones. By means of a systematic perturbation theory in the time-scale ratio we extract a reduced dynamics in terms of the slow variables only, valid after an initial transient period....
Persistent link: https://www.econbiz.de/10011058029
We consider linear dynamical systems with motions characterized by two different time-scales. In practice the dynamical matrix in the phenomenological equations of motion often exhibits a strong coupling of the slow and fast variables. It is shown on the basis of the Onsager symmetry relations...
Persistent link: https://www.econbiz.de/10011059070
We study thermodynamic systems near equilibrium described by both slow and fast variables. A reduced relaxation matrix for the slow variables can be obtained from the full relaxation matrix by a systematic elimination of the fast variables. When the full relaxation matrix possesses...
Persistent link: https://www.econbiz.de/10011061996
A formal analogy between the linear Chapman-Enskog procedure and a variant of the perturbation theory of degenerate levels, as presented by C. Bloch, is established. The analogy is than exploited to obtain closed expressions for the Chapman-Enskog special solutions to all orders in the...
Persistent link: https://www.econbiz.de/10011064030
To test and to complement the moment method for solving kinetic equations in the space outside of a sphere that absorbs one component out of a gas mixture, we develop a solution method especially suitable for radii smaller or not much larger than a mean free path. The method is used to calculate...
Persistent link: https://www.econbiz.de/10010874654
We study stationary solutions of the Fokker-Planck equation for velocity and position of a Brownian particle in the presence of a constant external field and a completely or selectively absorbing plane wall. Adapting a procedure used earlier for the field-free case, we determine analytically a...
Persistent link: https://www.econbiz.de/10010585071
The normal mode analysis of systems of linear macroscopic equations in irreversible thermodynamics is extended in several ways. When the characteristics equation has multiple roots, there may appear normal solutions that do not decay purely exponentially, but a closed form for the Green function...
Persistent link: https://www.econbiz.de/10010585106
The description using the Smoluchowski equation, on which the traditional theory of diffusion-controlled reactions is based, presupposes local equilibrium. Hence it must break down in the vicinity of an absorbing wall, where a kinetic boundary layer is formed. We explore in this paper the...
Persistent link: https://www.econbiz.de/10010585293