thermodiffusion of polymers and is shown to account for (i) the existence of both signs of the thermodiffusion coefficient of long …

The paper aims at a molecular understanding of thermodiffusion (the Ludwig–Soret effect) in a liquid binary mixture. To … thermodiffusion. The force driving thermodiffusion arises from Onsager’s reciprocity theorem in non-equilibrium thermodynamics: it is … explicit kinetic expression is given of the force driving thermodiffusion; it involves the interaction cross-section of the two …

shed light on thermodiffusion (the Ludwig–Soret effect), which often combines inhomogeneities of both kinds. Finally, a … limitation of the Lorentz picture of transport in accounting for thermodiffusion is outlined. …

presence of temperature gradients. It is found that temperature gradients not only introduce a thermophoresis force, but also … compared with each other and with the thermophoresis force. …

diffusion coefficients, is extended onto thermodiffusion coefficients and heat conductivities. The derivation of the expressions …

Thermodiffusion of particles suspended in a pure liquid is a thorny problem which has not yet received a solution … relative to the carrier fluid. Focussing on thermodiffusion, we show that the osmotic pressure is irrelevant and that … thermodiffusion cannot have but two distinct origins : the temperature dependence of the stress associated with the distorted particle …