Gorban, A.N.; Mirkes, E.M.; Yablonsky, G.S. - In: Physica A: Statistical Mechanics and its Applications 392 (2013) 6, pp. 1318-1335
For many complex real physicochemical systems, the detailed mechanism includes both reversible and irreversible reactions. Such systems are typical in homogeneous combustion and heterogeneous catalytic oxidation. Most complex enzyme reactions include irreversible steps. Classical thermodynamics...