Designing a Bifunctional Metal-Organic Framework by Tandem Post-Synthetic Modifications; an Efficient and Recyclable Catalyst for Suzuki-Miyaura Cross-Coupling Reaction
A new Cu/Pd bimetallic Cu-MOF-[Pd] was synthesized through covalent, dative and inorganic post-synthetic modifications. In order to achieve the Cu-MOF-[Pd], Zn-MOF (TMU-17-NH2) was initially selected and fabricated by grafting of salicylaldehyde via Schiff-base formation followed by complex formation with Pd(II). Then, the as-synthesis MOF, Zn-MOF-[Pd], was subjected as 3D-template to obtain Cu-MOF-[Pd] by transmetalation process. The Cu-MOF-[Pd] was characterized by FT-IR spectroscopy, atomic absorption spectroscopy (AAS), field emission scanning electron microscopy (FE-SEM), powder X-ray diffraction (PXRD), energy dispersive X-ray spectroscopy (EDS), and EDS mapping techniques. The feasibility of using Cu-MOF-[Pd] as a highly active recoverable catalyst was confirmed in the Suzuki–Miyaura cross-coupling reaction in a mixed water/ethanol solvent. The results show that this novel nano-composite could serve as an efficient bimetallic heterogeneous catalyst and reuse at least for 5 times without loss in activity
Year of publication: |
2020
|
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Authors: | Salahshournia, Behrang |
Other Persons: | Hamadi, Hosein (contributor) ; Nobakht, Valiollah (contributor) |
Publisher: |
[2020]: [S.l.] : SSRN |
Subject: | Kreislaufwirtschaft | Recycling | Effizienz | Efficiency | Produktgestaltung | Product design | Theorie | Theory |
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