Dry re-forming of methane to synthesis gas over lignite semicokes catalyst at high pressure
Fengbo Guo, Wanli Jia, Bin Hou, Yongfa Zhang
Dry re-forming of methane has been carried out in a high temperature-pressure reactor at different pressures, using Hongce lignite semicokes catalyst. The results show that CH4 and CO2 conversions are decreased as the reaction pressure increased, but both of them kept basically stable when the reaction pressure is between 0.3 and 1 MPa. The comparison shows that the effects of the temperature and the flow of reactant gas on dry re-forming of methane are consistent with between high pressure and atmospheric pressure. The ratio of CO/H2 decreased as the ratio of CH4/CO2 increased, yet the value of CO/H2 is always more than 1 at different pressures. Hongce lignite semicokes catalyst is characterized by FTIR, XRD, SEM and BET, and the analysis results reveled that the physical specific adsorption peak of CO2 at 2350 cm-1 is strengthened significantly at different pressures, the micropore area and volume of Hongce lignite semicokes reduced form 40.2 m2 g-1 and 0.019 cm3 g-1 to 34.9 m2 g-1 and 0.017 cm3 g-1, respectively. Hongce lignite semicokes catalyst exhibited better activity and stability within 0.3-1 MPa range.
Year of publication: |
November 2016
|
---|---|
Authors: | Guo, Fengbo ; Jia, Wanli ; Hou, Bin ; Zhang, Yongfa |
Published in: |
Energy reports. - Amsterdam [u.a.] : Elsevier, ISSN 2352-4847, ZDB-ID 2814795-9. - Vol. 2.2016, p. 163-170
|
Subject: | Catalytic activity | Dry re-forming of methane | High temperature-pressure reactor | Lignite semi-cokes |
Saved in:
freely available
Type of publication: | Article |
---|---|
Type of publication (narrower categories): | Aufsatz in Zeitschrift ; Article in journal |
Language: | English |
Other identifiers: | 10.1016/j.egyr.2016.04.002 [DOI] hdl:10419/187847 [Handle] |
Source: | ECONIS - Online Catalogue of the ZBW |
Persistent link: https://www.econbiz.de/10011863669
Saved in favorites
Similar items by subject
-
Dry re-forming of methane to synthesis gas over lignite semicokes catalyst at high pressure
Guo, Fengbo, (2016)
- More ...
Similar items by person