Note on the stochastic theory of a self-catalytic chemical reaction. I
By using the spectral theory of the master equation, it is shown generally that a self-catalytic chemical system may evolve according to two widely different time scales in this case. The shorter one describes the evolution towards a quasi-stationary state which is the stochastic equivalent of the macroscopic stationary state. The larger time characterizes the final evolution towards total absorption; it is coarsely evaluated for an arbitrary system and more precisely for a non step-by-step reaction. Detailed application to step-by-step reactions is given in a second article.
| Year of publication: |
1981
|
|---|---|
| Authors: | Dambrine, S. ; Moreau, M. |
| Published in: |
Physica A: Statistical Mechanics and its Applications. - Elsevier, ISSN 0378-4371. - Vol. 106.1981, 3, p. 559-573
|
| Publisher: |
Elsevier |
Saved in:
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