Reagent-Free Electrokinetic Remediation Coupled with Anode Oxidation for the Treatment of Phenanthrene Polluted Soil

Electrokinetic in-situ chemical oxidation (EK-ISCO) has attracted much attention during remediation of organic contaminated soil. Oxidants in EK-ISCO brings high cost and negative effects on soil physicochemical properties. In this study, a novel approach of combined electrokinetic treatment and anode oxidation was investigated to remediate phenanthrene polluted soils without adding oxidants. The fabricated Ti4O7 acted as anode, and could generate •OH at the rate of 9.31×10-7 mol h-1 at current 5.10 mA cm-2 through direct H2O electrolysis. Electro-osmotic flow (EOF) was used to transport phenanthrene to anode for the subsequent degradation. Sandy soil, fluvo-aquic soil sample and red soil were selected as typical soil samples, because pH and buffer capacity were two important factors affecting the direction of EOF. Strategies were developed to regulate the direction of EOF, including adding CEM membrane, maintaining soil pH at 3.5-4.0 and mixing solution from anode and cathode chambers. After treatment, more than 81.9% of phenanthrene was removed without adding any oxidants, and the remediated soil had low toxicity for lolium perenne growth based on 3-d cultivation results. The results indicated that EK-AO had the advantage of less energy consumption and superior environmental friendliness than traditional EK-ISCO