Violation of the electroneutrality condition in confined unsymmetrical electrolytes
The three-point extension hypernetted chain-mean spherical theory of liquids is solved for a system formed by two charged plates immersed in a model unsymmetrical electrolyte. The charge on the plates is fixed as a function of the distance between the plates. The extent to which the local electroneutrality condition is not satisfied is studied. The plate-plate force is calculated and compared to that for confined symmetrical electrolytes.
Year of publication: |
1996
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Authors: | Lozada-Cassou, Marcelo ; Olivares, Wilmer ; Sulbarán, Belky ; Jiang, Yu |
Published in: |
Physica A: Statistical Mechanics and its Applications. - Elsevier, ISSN 0378-4371. - Vol. 231.1996, 1, p. 197-206
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Publisher: |
Elsevier |
Saved in:
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