Virial coefficients of the equation of state of a gas of nonspherical molecules II. Polar molecules
The second and third virial coefficients of polar gases have been calculated for a set of force parameters which has been found suitable to explain the dilute gas viscosity data. The influence of a large number of orientation dependent pair- and three-body nonadditive interactions have been taken into account. The relative contribution of each branch of pair and triplet interactions has been evaluated as a function of temperature. The theoretical results have been compared with the experimental data of NH3 and CH3F.
Year of publication: |
1977
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Authors: | Singh, S. ; Singh, Y. |
Published in: |
Physica A: Statistical Mechanics and its Applications. - Elsevier, ISSN 0378-4371. - Vol. 87.1977, 2, p. 344-353
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Publisher: |
Elsevier |
Saved in:
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