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The second dielectric virial coefficient is evaluated for nonspherical polar fluids and compared with the experimental data of NH3 and CH3F.
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The second and third virial coefficient of a gas of nonspherical molecules of arbitrary symmetry have been calculated for a set of force parameters which has been found suitable to explain the dilute gas viscosity data. The influence of a large number of orientation dependent pair- and...
Persistent link: https://www.econbiz.de/10010584948
The second and third virial coefficients of polar gases have been calculated for a set of force parameters which has been found suitable to explain the dilute gas viscosity data. The influence of a large number of orientation dependent pair- and three-body nonadditive interactions have been...
Persistent link: https://www.econbiz.de/10010584999
The thermodynamic perturbation theory in which all angle-dependent interactions are considered as a perturbation of the central potential is applied to study the equilibrium properties of a fluid composed of non-axial molecules. The influence of a large number of anisotropic pair and three-body...
Persistent link: https://www.econbiz.de/10010585221